Testing

rubber

Full migration

Special migration of aromatic amines

AP (2004)4 Rubber

Nitrosamine and nitroso substance content

Silicone Rubber

Full migration (deionized water, 3%   acetic acid, 10% ethanol, olive oil substitute isooctane + 95% ethanol)

AP(2004)5 Silicone Rubber

Such as SBS, TPR, TPE, rubber, silicone,   etc.

Distilled water extract

N-hexane extract

21CFR 177.2600
  Rubber articles intended for
  repeated use

Silicone sealing ring

Water-extracted chloroform soluble   extract

Chloroform soluble extract of 8% ethanol   extract

Chloroform soluble extract extracted by   n-heptane

21CFR 177.1210

Closure with sealing gaskets

rubber products

Total migration

Arrêté du 5 août 2020
  DGCCRF No.2004/64

Total volatile organic matter (VOC)

Nitrosamine and nitroso substance content   (pacifier)

Migration of nitrosamines and nitroso   substances

Primary aromatic amine migration

Total migration amount of primary   aromatic amine and secondary aromatic amine

Specific migration of formaldehyde

Total specific migration of formaldehyde and   hexamethylenetetramine

POV

Migration of heavy metals (barium,   copper, aluminum, zinc)

Heavy metal content (lead, cadmium,   arsenic, antimony, mercury)

Silicone products

Full migration

DM-4B-COM-003-v01
  DGCCRF No.2004/64

POV

Total organic matter volatile

Specific migration of organotin in 3%   acetic acid

Rubber,   TPR, TPE
  Rubber or elastomer products

Sensory   test

LFGB 30&31

Full   migration

Color migration

Specific   migration of primary aromatic amines

Specific   migration of nitrosamines

Content   of nitrosamines and nitroso substances (only for pacifiers, pacifiers, tooth   rings, mouthguards)

Total   lead, total cadmium

Silicone   Rubber

Sensory   test

LFGB 30&31

Color   migration

Full   migration

Peroxide   value test

Total   organic volatile matter

Total   lead and total cadmium

Rubber   materials and products

Senses

Total migration: -10% ethanol, 4% acetic   acid

20% ethanol, 50% ethanol

Potassium permanganate consumption

Heavy metals (calculated as Pb)

GB 4806.11-2016

Rubber   pacifier

Senses

Total   migration capacity distilled water, 4% acetic acid, 50% ethanol

Potassium   permanganate consumption

Heavy   metals (as lead)

Zinc   (Zn) migration

2,6-Di-tert-butyl   p-cresol migration

2,2’-methylenebis-(4-methyl-6-tert-butylphenol)   migration

Remarks:   The items in this column are only applicable to natural rubber and   cis-1,4-polyisoprene rubber pacifiers (that is, latex pacifiers in daily use)

N-nitrosamine   release

N-nitrosamine   product release

Volatile   substances

Remarks:   The items in this column are only applicable to silicone rubber pacifiers   (that is, silicone pacifiers in daily use). "

GB 4806.2-2015